The energy E of the partical within the well must be invariant with respect to coordinate system chosen by the observer. Therefore, its value must be derived in a fashion independent of the position of the well. The Bohr-Sommerfeld rule for the quantizaation of momentum allows for this derivation of the value of k in a frame-independent fashion.1

It can be shown that for a constant potential V(x) in a region with turning points xa and xb, the ground state energy E1 can be calculated from

xaxbk1dx=nπ

with

k1=2mE12

as a generalization of the Bohr-Sommerfeld quantizatuion rule.2

The next set of energy levels is given by

x0x0+Lkndx=nπn=2,3

which gives

(1)kn=nπLn=±1,±2,±3,

Keeping in mind that

(2)kn=2mEn2

Substituting Eq.(2) into Eq.(1) and solving for E results in

En=n2π222mL2

The quantization of energy is the same as that noted in the traditional approach. However, obtaining the result from the Wilson-Sommerfeld rule relies on the length L of the well which is invariant.

  1. HA Mavromatis, {\em Exercises in Quanum Mechanics. Wilson-Sommerfeld Quantization Condition}. vol.2. 1987. Chapter 1, pg.1. [↩]
  2. F.A. Serrano, “Qiang-Dong proper quantization rule and its applications to exactly solvable quantum systems” J. Math. Phys. 51, 082103 (2010); https://doi.org/10.1063/1.3466802. [↩]